On passing a gas, '$\mathrm{X}$', through Nessler's regent, a brown precipitate is obtained. The gas '$\mathrm{X}$' is

Match List I with List II

Choose the correct answer from the options given below:

Which of the following acts as a strong reducing agent? (Atomic number: $\mathrm{Ce}=58, \mathrm{Eu}=63, \mathrm{Gd}=64, \mathrm{Lu}=71$)

Given below are two statements:

Statement I : Fluorine has most negative electron gain enthalpy in its group.

Statement II : Oxygen has least negative electron gain enthalpy in its group.

In the light of the above statements, choose the most appropriate from the options given below

According to IUPAC system, the compound

is named as

Match List I with List II

Choose the correct answer from the options given below:

The element having the highest first ionization enthalpy is

Which of the following statements are correct about $\mathrm{Zn}, \mathrm{Cd}$ and $\mathrm{Hg}$ ?

A. They exhibit high enthalpy of atomization as the d-subshell is full.

B. $\mathrm{Zn}$ and $\mathrm{Cd}$ do not show variable oxidation state while $\mathrm{Hg}$ shows $+\mathrm{I}$ and $+\mathrm{II}$.

C. Compounds of $\mathrm{Zn}, \mathrm{Cd}$ and $\mathrm{Hg}$ are paramagnetic in nature.

D. $\mathrm{Zn}, \mathrm{Cd}$ and $\mathrm{Hg}$ are called soft metals.

Choose the most appropriate from the options given below:

The ascending acidity order of the following H atoms is

The correct IUPAC name of $\mathrm{K}_2 \mathrm{MnO}_4$ is

Identify the reagents used for the following conversion

Chromatographic technique/s based on the principle of differential adsorption is / are

A. Column chromatography

B. Thin layer chromatography

C. Paper chromatography

Choose the most appropriate answer from the options given below:

Which of the following reaction is correct?

Anomalous behavior of oxygen is due to its

Which one of the following will show geometrical isomerism?

A reagent which gives brilliant red precipitate with Nickel ions in basic medium is

Phenol treated with chloroform in presence of sodium hydroxide, which further hydrolyzed in presence of an acid results

Match List I with List II

Choose the correct answer from the options given below:

The product A formed in the following reaction is

Alkyl halide is converted into alkyl isocyanide by reaction with

The total number of molecules with zero dipole moment among $\mathrm{CH}_4, \mathrm{BF}_3, \mathrm{H}_2 \mathrm{O}, \mathrm{HF}, \mathrm{NH}_3, \mathrm{CO}_2$ and $\mathrm{SO}_2$ is ________.

Standard enthalpy of vapourisation for $\mathrm{CCl}_4$ is $30.5 \mathrm{~kJ} \mathrm{~mol}^{-1}$. Heat required for vapourisation of $284 \mathrm{~g}$ of $\mathrm{CCl}_4$ at constant temperature is ________ $\mathrm{kJ}$.

(Given molar mass in $\mathrm{g} \mathrm{mol}^{-1} ; \mathrm{C}=12, \mathrm{Cl}=35.5$)

If $50 \mathrm{~mL}$ of $0.5 \mathrm{M}$ oxalic acid is required to neutralise $25 \mathrm{~mL}$ of $\mathrm{NaOH}$ solution, the amount of $\mathrm{NaOH}$ in $50 \mathrm{~mL}$ of given $\mathrm{NaOH}$ solution is ______ g.

The following concentrations were observed at $500 \mathrm{~K}$ for the formation of $\mathrm{NH}_3$ from $\mathrm{N}_2$ and $\mathrm{H}_2$. At equilibrium ; $\left[\mathrm{N}_2\right]=2 \times 10^{-2} \mathrm{M},\left[\mathrm{H}_2\right]=3 \times 10^{-2} \mathrm{M}$ and $\left[\mathrm{NH}_3\right]=1.5 \times 10^{-2} \mathrm{M}$. Equilibrium constant for the reaction is ________.

A constant current was passed through a solution of $\mathrm{AuCl}_4^{-}$ ion between gold electrodes. After a period of 10.0 minutes, the increase in mass of cathode was $1.314 \mathrm{~g}$. The total charge passed through the solution is _______ $\times 10^{-2} \mathrm{~F}$.

(Given atomic mass of $\mathrm{Au}=197$)

The total number of anti bonding molecular orbitals, formed from $2 s$ and $2 p$ atomic orbitals in a diatomic molecule is _______.

The half-life of radioisotope bromine - 82 is 36 hours. The fraction which remains after one day is ________ $\times 10^{-2}$.

(Given antilog $0.2006=1.587$)

The total number of 'Sigma' and 'Pi' bonds in 2-formylhex-4-enoic acid is _________.

The oxidation number of iron in the compound formed during brown ring test for NO$_3^-$ iron is ________.

Molality of 0.8 M H$_2$SO$_4$ solution (density 1.06 g cm$^{-3}$) is ________ $\times10^{-3}$ m.

Number of ways of arranging 8 identical books into 4 identical shelves where any number of shelves may remain empty is equal to

Let $\mathrm{A}$ be the point of intersection of the lines $3 x+2 y=14,5 x-y=6$ and $\mathrm{B}$ be the point of intersection of the lines $4 x+3 y=8,6 x+y=5$. The distance of the point $P(5,-2)$ from the line $\mathrm{AB}$ is

If $\int \frac{\sin ^{\frac{3}{2}} x+\cos ^{\frac{3}{2}} x}{\sqrt{\sin ^3 x \cos ^3 x \sin (x-\theta)}} d x=A \sqrt{\cos \theta \tan x-\sin \theta}+B \sqrt{\cos \theta-\sin \theta \cot x}+C$, where $C$ is the integration constant, then $A B$ is equal to

The distance of the point $(2,3)$ from the line $2 x-3 y+28=0$, measured parallel to the line $\sqrt{3} x-y+1=0$, is equal to

Let a unit vector $\hat{u}=x \hat{i}+y \hat{j}+z \hat{k}$ make angles $\frac{\pi}{2}, \frac{\pi}{3}$ and $\frac{2 \pi}{3}$ with the vectors $\frac{1}{\sqrt{2}} \hat{i}+\frac{1}{\sqrt{2}} \hat{k}, \frac{1}{\sqrt{2}} \hat{j}+\frac{1}{\sqrt{2}} \hat{k}$ and $\frac{1}{\sqrt{2}} \hat{i}+\frac{1}{\sqrt{2}} \hat{j}$ respectively. If $\vec{v}=\frac{1}{\sqrt{2}} \hat{i}+\frac{1}{\sqrt{2}} \hat{j}+\frac{1}{\sqrt{2}} \hat{k}$ then $|\hat{u}-\vec{v}|^2$ is equal to

The function $f(x)=\frac{x}{x^2-6 x-16}, x \in \mathbb{R}-\{-2,8\}$

If R is the smallest equivalence relation on the set $\{1,2,3,4\}$ such that $\{(1,2),(1,3)\} \subset \mathrm{R}$, then the number of elements in $\mathrm{R}$ is __________.

If the mean and variance of five observations are $\frac{24}{5}$ and $\frac{194}{25}$ respectively and the mean of the first four observations is $\frac{7}{2}$, then the variance of the first four observations in equal to

Let $\mathrm{P}(3,2,3), \mathrm{Q}(4,6,2)$ and $\mathrm{R}(7,3,2)$ be the vertices of $\triangle \mathrm{PQR}$. Then, the angle $\angle \mathrm{QPR}$ is

$\text { Let } y=\log _e\left(\frac{1-x^2}{1+x^2}\right),-1 < x<1 \text {. Then at } x=\frac{1}{2} \text {, the value of } 225\left(y^{\prime}-y^{\prime \prime}\right) \text { is equal to }$

If $\log _e \mathrm{a}, \log _e \mathrm{~b}, \log _e \mathrm{c}$ are in an A.P. and $\log _e \mathrm{a}-\log _e 2 \mathrm{~b}, \log _e 2 \mathrm{~b}-\log _e 3 \mathrm{c}, \log _e 3 \mathrm{c} -\log _e$ a are also in an A.P, then $a: b: c$ is equal to

If $\sin \left(\frac{y}{x}\right)=\log _e|x|+\frac{\alpha}{2}$ is the solution of the differential equation $x \cos \left(\frac{y}{x}\right) \frac{d y}{d x}=y \cos \left(\frac{y}{x}\right)+x$ and $y(1)=\frac{\pi}{3}$, then $\alpha^2$ is equal to

An integer is chosen at random from the integers $1,2,3, \ldots, 50$. The probability that the chosen integer is a multiple of atleast one of 4, 6 and 7 is

Let $\overrightarrow{O A}=\vec{a}, \overrightarrow{O B}=12 \vec{a}+4 \vec{b} \text { and } \overrightarrow{O C}=\vec{b}$, where O is the origin. If S is the parallelogram with adjacent sides OA and OC, then $\mathrm{{{area\,of\,the\,quadrilateral\,OA\,BC} \over {area\,of\,S}}}$ is equal to _________.

The function $f(x)=2 x+3(x)^{\frac{2}{3}}, x \in \mathbb{R}$, has

If each term of a geometric progression $a_1, a_2, a_3, \ldots$ with $a_1=\frac{1}{8}$ and $a_2 \neq a_1$, is the arithmetic mean of the next two terms and $S_n=a_1+a_2+\ldots . .+a_n$, then $S_{20}-S_{18}$ is equal to

Let $\mathrm{r}$ and $\theta$ respectively be the modulus and amplitude of the complex number $z=2-i\left(2 \tan \frac{5 \pi}{8}\right)$, then $(\mathrm{r}, \theta)$ is equal to

The sum of the solutions $x \in \mathbb{R}$ of the equation $\frac{3 \cos 2 x+\cos ^3 2 x}{\cos ^6 x-\sin ^6 x}=x^3-x^2+6$ is

Let $x=\frac{m}{n}$ ($m, n$ are co-prime natural numbers) be a solution of the equation $\cos \left(2 \sin ^{-1} x\right)=\frac{1}{9}$ and let $\alpha, \beta(\alpha >\beta)$ be the roots of the equation $m x^2-n x-m+ n=0$. Then the point $(\alpha, \beta)$ lies on the line

Let $A=\left[\begin{array}{ccc}2 & 1 & 2 \\ 6 & 2 & 11 \\ 3 & 3 & 2\end{array}\right]$ and $P=\left[\begin{array}{lll}1 & 2 & 0 \\ 5 & 0 & 2 \\ 7 & 1 & 5\end{array}\right]$. The sum of the prime factors of $\left|P^{-1} A P-2 I\right|$ is equal to

Let O be the origin, and M and $\mathrm{N}$ be the points on the lines $\frac{x-5}{4}=\frac{y-4}{1}=\frac{z-5}{3}$ and $\frac{x+8}{12}=\frac{y+2}{5}=\frac{z+11}{9}$ respectively such that $\mathrm{MN}$ is the shortest distance between the given lines. Then $\overrightarrow{O M} \cdot \overrightarrow{O N}$ is equal to _________.

Let the area of the region $\left\{(x, y): 0 \leq x \leq 3,0 \leq y \leq \min \left\{x^2+2,2 x+2\right\}\right\}$ be A. Then $12 \mathrm{~A}$ is equal to __________.

Let the set $C=\left\{(x, y) \mid x^2-2^y=2023, x, y \in \mathbb{N}\right\}$. Then \sum_\limits{(x, y) \in C}(x+y) is equal to _________.

Let the slope of the line $45 x+5 y+3=0$ be $27 r_1+\frac{9 r_2}{2}$ for some $r_1, r_2 \in \mathbb{R}$. Then \lim _\limits{x \rightarrow 3}\left(\int_3^x \frac{8 t^2}{\frac{3 r_2 x}{2}-r_2 x^2-r_1 x^3-3 x} d t\right) is equal to _________.

Let $\alpha, \beta$ be the roots of the equation $x^2-\sqrt{6} x+3=0$ such that $\operatorname{Im}(\alpha)>\operatorname{Im}(\beta)$. Let $a, b$ be integers not divisible by 3 and $n$ be a natural number such that $\frac{\alpha^{99}}{\beta}+\alpha^{98}=3^n(a+i b), i=\sqrt{-1}$. Then $n+a+b$ is equal to __________.

Let for any three distinct consecutive terms $a, b, c$ of an A.P, the lines $a x+b y+c=0$ be concurrent at the point $P$ and $Q(\alpha, \beta)$ be a point such that the system of equations

$$\begin{aligned} & x+y+z=6, \\ & 2 x+5 y+\alpha z=\beta \text { and } \end{aligned}$$

$x+2 y+3 z=4$, has infinitely many solutions. Then $(P Q)^2$ is equal to _________.

Let $P(\alpha, \beta)$ be a point on the parabola $y^2=4 x$. If $P$ also lies on the chord of the parabola $x^2=8 y$ whose mid point is $\left(1, \frac{5}{4}\right)$, then $(\alpha-28)(\beta-8)$ is equal to _________.

Remainder when $64^{32^{32}}$ is divided by 9 is equal to ________.

Let f(x)=\sqrt{\lim _\limits{r \rightarrow x}\left\{\frac{2 r^2\left[(f(r))^2-f(x) f(r)\right]}{r^2-x^2}-r^3 e^{\frac{f(r)}{r}}\right\}} be differentiable in $(-\infty, 0) \cup(0, \infty)$ and $f(1)=1$. Then the value of ea, such that $f(a)=0$, is equal to _________.

If \int_\limits{\frac{\pi}{6}}^{\frac{\pi}{3}} \sqrt{1-\sin 2 x} d x=\alpha+\beta \sqrt{2}+\gamma \sqrt{3}, where $\alpha, \beta$ and $\gamma$ are rational numbers, then $3 \alpha+4 \beta-\gamma$ is equal to _________.

A small liquid drop of radius $R$ is divided into 27 identical liquid drops. If the surface tension is $T$, then the work done in the process will be:

In the given circuit, the current in resistance R$_3$ is :

A physical quantity $Q$ is found to depend on quantities $a, b, c$ by the relation $Q=\frac{a^4 b^3}{c^2}$. The percentage error in $a, b$ and $c$ are $3 \%, 4 \%$ and $5 \%$ respectively. Then, the percentage error in $Q$ is :

A stone of mass $900 \mathrm{~g}$ is tied to a string and moved in a vertical circle of radius $1 \mathrm{~m}$ making $10 \mathrm{~rpm}$. The tension in the string, when the stone is at the lowest point is (if $\pi^2=9.8$ and $g=9.8 \mathrm{~m} / \mathrm{s}^2$) :

The truth table for this given circuit is :

A bob of mass '$m$' is suspended by a light string of length '$L$'. It is imparted a minimum horizontal velocity at the lowest point $A$ such that it just completes half circle reaching the top most position B. The ratio of kinetic energies $\frac{(K . E)_A}{(K . E)_B}$ is :

An electric field is given by $(6 \hat{i}+5 \hat{j}+3 \hat{k}) \mathrm{N} / \mathrm{C}$. The electric flux through a surface area $30 \hat{i} \mathrm{~m}^2$ lying in YZ-plane (in SI unit) is :

A planet takes 200 days to complete one revolution around the Sun. If the distance of the planet from Sun is reduced to one fourth of the original distance, how many days will it take to complete one revolution :

A wire of length $L$ and radius $r$ is clamped at one end. If its other end is pulled by a force $F$, its length increases by $l$. If the radius of the wire and the applied force both are reduced to half of their original values keeping original length constant, the increase in length will become:

The temperature of a gas having $2.0 \times 10^{25}$ molecules per cubic meter at $1.38 \mathrm{~atm}$ (Given, $\mathrm{k}=1.38 \times 10^{-23} \mathrm{JK}^{-1}$) is :

If the distance between object and its two times magnified virtual image produced by a curved mirror is $15 \mathrm{~cm}$, the focal length of the mirror must be:

A plane electromagnetic wave of frequency $35 \mathrm{~MHz}$ travels in free space along the $X$-direction. At a particular point (in space and time) $\vec{E}=9.6 \hat{j} \mathrm{~V} / \mathrm{m}$. The value of magnetic field at this point is :

In an a.c. circuit, voltage and current are given by:

$V=100 \sin (100 t) V$ and $I=100 \sin \left(100 t+\frac{\pi}{3}\right) \mathrm{mA}$ respectively.

The average power dissipated in one cycle is:

A particle is moving in a straight line. The variation of position '$x$' as a function of time '$t$' is given as $x=\left(t^3-6 t^2+20 t+15\right) m$. The velocity of the body when its acceleration becomes zero is :

The bob of a pendulum was released from a horizontal position. The length of the pendulum is $10 \mathrm{~m}$. If it dissipates $10 \%$ of its initial energy against air resistance, the speed with which the bob arrives at the lowest point is:

[Use, $\mathrm{g}: 10 \mathrm{~ms}^{-2}$]

$N$ moles of a polyatomic gas $(f=6)$ must be mixed with two moles of a monoatomic gas so that the mixture behaves as a diatomic gas. The value of $N$ is :

In Young's double slit experiment, light from two identical sources are superimposing on a screen. The path difference between the two lights reaching at a point on the screen is $7 \lambda / 4$. The ratio of intensity of fringe at this point with respect to the maximum intensity of the fringe is :

Given below are two statements:

Statement I : Most of the mass of the atom and all its positive charge are concentrated in a tiny nucleus and the electrons revolve around it, is Rutherford's model.

Statement II : An atom is a spherical cloud of positive charges with electrons embedded in it, is a special case of Rutherford's model.

In the light of the above statements, choose the most appropriate from the options given below

Two sources of light emit with a power of $200 \mathrm{~W}$. The ratio of number of photons of visible light emitted by each source having wavelengths $300 \mathrm{~nm}$ and $500 \mathrm{~nm}$ respectively, will be :

Two particles $X$ and $Y$ having equal charges are being accelerated through the sat potential difference. Thereafter they enter normally in a region of uniform magnetic field and describes circular paths of radii $R_1$ and $R_2$ respectively. The mass ratio of $X$ and $Y$ is :

In the given circuit, the current flowing through the resistance $20 \Omega$ is $0.3 \mathrm{~A}$, while the ammeter reads $0.9 \mathrm{~A}$. The value of $\mathrm{R}_1$ is _________ $\Omega$.

In the given figure, the charge stored in $6 \mu F$ capacitor, when points $A$ and $B$ are joined by a connecting wire is __________ $\mu C$.

In a single slit diffraction pattern, a light of wavelength 6000$\mathop A\limits^o$ is used. The distance between the first and third minima in the diffraction pattern is found to be $3 \mathrm{~mm}$ when the screen in placed $50 \mathrm{~cm}$ away from slits. The width of the slit is _________ $\times 10^{-4} \mathrm{~m}$.

A body of mass $5 \mathrm{~kg}$ moving with a uniform speed $3 \sqrt{2} \mathrm{~ms}^{-1}$ in $X-Y$ plane along the line $y=x+4$. The angular momentum of the particle about the origin will be _________ $\mathrm{kg} \mathrm{~m}^2 \mathrm{~s}^{-1}$.

Hydrogen atom is bombarded with electrons accelerated through a potential difference of $\mathrm{V}$, which causes excitation of hydrogen atoms. If the experiment is being performed at $\mathrm{T}=0 \mathrm{~K}$, the minimum potential difference needed to observe any Balmer series lines in the emission spectra will be $\frac{\alpha}{10} \mathrm{~V}$, where $\alpha=$ __________.

A simple harmonic oscillator has an amplitude $A$ and time period $6 \pi$ second. Assuming the oscillation starts from its mean position, the time required by it to travel from $x=$ A to $x=\frac{\sqrt{3}}{2}$ A will be $\frac{\pi}{x} \mathrm{~s}$, where $x=$ _________.

Two metallic wires $P$ and $Q$ have same volume and are made up of same material. If their area of cross sections are in the ratio $4: 1$ and force $F_1$ is applied to $P$, an extension of $\Delta l$ is produced. The force which is required to produce same extension in $Q$ is $\mathrm{F}_2$.

The value of $\frac{F_1}{F_2}$ is _________.

A particle is moving in a circle of radius $50 \mathrm{~cm}$ in such a way that at any instant the normal and tangential components of it's acceleration are equal. If its speed at $\mathrm{t}=0$ is $4 \mathrm{~m} / \mathrm{s}$, the time taken to complete the first revolution will be $\frac{1}{\alpha}\left[1-e^{-2 \pi}\right] \mathrm{s}$, where $\alpha=$ _________.

A charge of $4.0 \mu \mathrm{C}$ is moving with a velocity of $4.0 \times 10^6 \mathrm{~ms}^{-1}$ along the positive $y$ axis under a magnetic field $\vec{B}$ of strength $(2 \hat{k}) \mathrm{T}$. The force acting on the charge is $x \hat{i} N$. The value of $x$ is __________.

A horizontal straight wire $5 \mathrm{~m}$ long extending from east to west falling freely at right angle to horizontal component of earths magnetic field $0.60 \times 10^{-4} \mathrm{~Wbm}^{-2}$. The instantaneous value of emf induced in the wire when its velocity is $10 \mathrm{~ms}^{-1}$ is _________ $\times 10^{-3} \mathrm{~V}$.