The technique used for purification of steam volatile water immiscible substances is :

Match List - I with List - II.

	List - I (Reaction)		List - II (Reagent(s))
(A)		(I)	$\mathrm{Na_2Cr_2O_7,H_2SO_4}$
(B)		(II)	(i) $\mathrm(NaOH)$, (ii) $\mathrm{CH_3Cl}$
(C)		(III)	(i) $\mathrm{NaOH,CHCl_3}$, (ii) $\mathrm{NaOH}$, (iii) $\mathrm{HCl}$
(D)		(IV)	(i) $\mathrm{NaOH}$, (ii) $\mathrm{CO_2}$, (iii) $\mathrm{HCl}$

Choose the correct answer from the options given below :

Which of the following cannot function as an oxidising agent?

The number of non-polar molecules from the following is _________. $\mathrm{HF}, \mathrm{H}_2 \mathrm{O}, \mathrm{SO}_2, \mathrm{H}_2, \mathrm{CO}_2, \mathrm{CH}_4, \mathrm{NH}_3, \mathrm{HCl}, \mathrm{CHCl}_3, \mathrm{BF}_3$

Considering only the principal values of inverse trigonometric functions, the number of positive real values of $x$ satisfying $\tan ^{-1}(x)+\tan ^{-1}(2 x)=\frac{\pi}{4}$ is :

Consider the function $f:(0,2) \rightarrow \mathbf{R}$ defined by $f(x)=\frac{x}{2}+\frac{2}{x}$ and the function $g(x)$ defined by

$$g(x)=\left\{\begin{array}{ll} \min \lfloor f(t)\}, & 0<\mathrm{t} \leq x \text { and } 0 < x \leq 1 \\ \frac{3}{2}+x, & 1 < x < 2 \end{array} .\right. \text { Then, }$$

If $\alpha, \beta$ are the roots of the equation, $x^2-x-1=0$ and $S_n=2023 \alpha^n+2024 \beta^n$, then :

Let $e_1$ be the eccentricity of the hyperbola $\frac{x^2}{16}-\frac{y^2}{9}=1$ and $e_2$ be the eccentricity of the ellipse $\frac{x^2}{a^2}+\frac{y^2}{b^2}=1, \mathrm{a} > \mathrm{b}$, which passes through the foci of the hyperbola. If $\mathrm{e}_1 \mathrm{e}_2=1$, then the length of the chord of the ellipse parallel to the $x$-axis and passing through $(0,2)$ is :

The values of $\alpha$, for which $\left|\begin{array}{ccc}1 & \frac{3}{2} & \alpha+\frac{3}{2} \\ 1 & \frac{1}{3} & \alpha+\frac{1}{3} \\ 2 \alpha+3 & 3 \alpha+1 & 0\end{array}\right|=0$, lie in the interval

The position vectors of the vertices $\mathrm{A}, \mathrm{B}$ and $\mathrm{C}$ of a triangle are $2 \hat{i}-3 \hat{j}+3 \hat{k}, 2 \hat{i}+2 \hat{j}+3 \hat{k}$ and $-\hat{i}+\hat{j}+3 \hat{k}$ respectively. Let $l$ denotes the length of the angle bisector $\mathrm{AD}$ of $\angle \mathrm{BAC}$ where $\mathrm{D}$ is on the line segment $\mathrm{BC}$, then $2 l^2$ equals :

Let $A$ be a $2 \times 2$ real matrix and $I$ be the identity matrix of order 2. If the roots of the equation $|\mathrm{A}-x \mathrm{I}|=0$ be $-1$ and 3, then the sum of the diagonal elements of the matrix $\mathrm{A}^2$ is

Consider a circle $(x-\alpha)^2+(y-\beta)^2=50$, where $\alpha, \beta>0$. If the circle touches the line $y+x=0$ at the point $P$, whose distance from the origin is $4 \sqrt{2}$, then $(\alpha+\beta)^2$ is equal to __________.

Given below are two statements :

Statement (I) : The limiting force of static friction depends on the area of contact and independent of materials.

Statement (II) : The limiting force of kinetic friction is independent of the area of contact and depends on materials.

In the light of the above statements, choose the most appropriate answer from the options given below :

A bullet is fired into a fixed target looses one third of its velocity after travelling $4 \mathrm{~cm}$. It penetrates further $\mathrm{D} \times 10^{-3} \mathrm{~m}$ before coming to rest. The value of $\mathrm{D}$ is :

An object is placed in a medium of refractive index 3 . An electromagnetic wave of intensity $6 \times 10^8 \mathrm{~W} / \mathrm{m}^2$ falls normally on the object and it is absorbed completely. The radiation pressure on the object would be (speed of light in free space $=3 \times 10^8 \mathrm{~m} / \mathrm{s}$ ) :

The total kinetic energy of 1 mole of oxygen at $27^{\circ} \mathrm{C}$ is : [Use universal gas constant $(R)=8.31 \mathrm{~J} /$ mole K]

A closed organ pipe $150 \mathrm{~cm}$ long gives 7 beats per second with an open organ pipe of length $350 \mathrm{~cm}$, both vibrating in fundamental mode. The velocity of sound is __________ $\mathrm{m} / \mathrm{s}$.

Two charges of $-4 \mu \mathrm{C}$ and $+4 \mu \mathrm{C}$ are placed at the points $\mathrm{A}(1,0,4) \mathrm{m}$ and $\mathrm{B}(2,-1,5) \mathrm{m}$ located in an electric field $\overrightarrow{\mathrm{E}}=0.20 \hat{i} \mathrm{~V} / \mathrm{cm}$. The magnitude of the torque acting on the dipole is $8 \sqrt{\alpha} \times 10^{-5} \mathrm{Nm}$, where $\alpha=$ _________.

The order of relative stability of the contributing structure is :

Choose the correct answer from the options given below :

Identify from the following species in which $\mathrm{d}^2 \mathrm{sp}^3$ hybridization is shown by central atom :

Given below are two statements :

Statement (I) : In the Lanthanoids, the formation $\mathrm{Ce}^{+4}$ is favoured by its noble gas configuration.

Statement (II) : $\mathrm{Ce}^{+4}$ is a strong oxidant reverting to the common +3 state.

In the light of the above statements, choose the most appropriate answer from the options given below :

The molecular formula of second homologue in the homologous series of mono carboxylic acids is

1 mole of $\mathrm{PbS}$ is oxidised by "$\mathrm{X}$" moles of $\mathrm{O}_3$ to get "$\mathrm{Y}$" moles of $\mathrm{O}_2$. $\mathrm{X}+\mathrm{Y}=$ _________.

Time required for completion of $99.9 \%$ of a First order reaction is ________ times of half life $\left(t_{1 / 2}\right)$ of the reaction.

For a certain thermochemical reaction $\mathrm{M} \rightarrow \mathrm{N}$ at $\mathrm{T}=400 \mathrm{~K}, \Delta \mathrm{H}^{\ominus}=77.2 \mathrm{~kJ} \mathrm{~mol}^{-1}, \Delta \mathrm{S}=122 \mathrm{~JK}^{-1}, \log$ equilibrium constant $(\log K)$ is __________ $\times 10^{-1}$.

Let the position vectors of the vertices $\mathrm{A}, \mathrm{B}$ and $\mathrm{C}$ of a triangle be $2 \hat{i}+2 \hat{j}+\hat{k}, \hat{i}+2 \hat{j}+2 \hat{k}$ and $2 \hat{i}+\hat{j}+2 \hat{k}$ respectively. Let $l_1, l_2$ and $l_3$ be the lengths of perpendiculars drawn from the ortho center of the triangle on the sides $\mathrm{AB}, \mathrm{BC}$ and $\mathrm{CA}$ respectively, then $l_1^2+l_2^2+l_3^2$ equals:

Let $f: \mathbf{R}-\left\{\frac{-1}{2}\right\} \rightarrow \mathbf{R}$ and $g: \mathbf{R}-\left\{\frac{-5}{2}\right\} \rightarrow \mathbf{R}$ be defined as $f(x)=\frac{2 x+3}{2 x+1}$ and $g(x)=\frac{|x|+1}{2 x+5}$. Then, the domain of the function fog is :

Let $\alpha=\frac{(4 !) !}{(4 !)^{3 !}}$ and $\beta=\frac{(5 !) !}{(5 !)^{4 !}}$. Then :

$\text { The integral } \int \frac{\left(x^8-x^2\right) \mathrm{d} x}{\left(x^{12}+3 x^6+1\right) \tan ^{-1}\left(x^3+\frac{1}{x^3}\right)} \text { is equal to : }$

For $0 < \mathrm{a} < 1$, the value of the integral \int_\limits0^\pi \frac{\mathrm{d} x}{1-2 \mathrm{a} \cos x+\mathrm{a}^2} is :

The mean and standard deviation of 15 observations were found to be 12 and 3 respectively. On rechecking it was found that an observation was read as 10 in place of 12 . If $\mu$ and $\sigma^2$ denote the mean and variance of the correct observations respectively, then $15\left(\mu+\mu^2+\sigma^2\right)$ is equal to __________.

The coefficient of $x^{2012}$ in the expansion of $(1-x)^{2008}\left(1+x+x^2\right)^{2007}$ is equal to _________.

Let the complex numbers $\alpha$ and $\frac{1}{\bar{\alpha}}$ lie on the circles $\left|z-z_0\right|^2=4$ and $\left|z-z_0\right|^2=16$ respectively, where $z_0=1+i$. Then, the value of $100|\alpha|^2$ is __________.

If the solution curve, of the differential equation $\frac{\mathrm{d} y}{\mathrm{~d} x}=\frac{x+y-2}{x-y}$ passing through the point $(2,1)$ is $\tan ^{-1}\left(\frac{y-1}{x-1}\right)-\frac{1}{\beta} \log _{\mathrm{e}}\left(\alpha+\left(\frac{y-1}{x-1}\right)^2\right)=\log _{\mathrm{e}}|x-1|$, then $5 \beta+\alpha$ is equal to __________.

Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R).

Assertion (A) : In Vernier calliper if positive zero error exists, then while taking measurements, the reading taken will be more than the actual reading.

Reason (R) : The zero error in Vernier Calliper might have happened due to manufacturing defect or due to rough handling.

In the light of the above statements, choose the correct answer from the options given below :

A heavy iron bar of weight $12 \mathrm{~kg}$ is having its one end on the ground and the other on the shoulder of a man. The rod makes an angle $60^{\circ}$ with the horizontal, the weight experienced by the man is :

The threshold frequency of a metal with work function $6.63 \mathrm{~eV}$ is :

Three voltmeters, all having different internal resistances are joined as shown in figure. When some potential difference is applied across $A$ and $B$, their readings are $V_1, V_2$ and $V_3$. Choose the correct option.

When a polaroid sheet is rotated between two crossed polaroids then the transmitted light intensity will be maximum for a rotation of :

Major product formed in the following reaction is a mixture of :

Bond line formula of HOCH(CN)$_2$ is :

$9.3 \mathrm{~g}$ of aniline is subjected to reaction with excess of acetic anhydride to prepare acetanilide. The mass of acetanilide produced if the reaction is $100 \%$ completed is _________ $\times 10^{-1} \mathrm{~g}$.

(Given molar mass in $\mathrm{g} \mathrm{~mol}^{-1}$

$$\begin{aligned} & \mathrm{N}: 14, \mathrm{O}: 16, \\ & \mathrm{C}: 12, \mathrm{H}: 1 \text { ) } \end{aligned}$$

Total number of ions from the following with noble gas configuration is _________. $\mathrm{Sr}^{2+}(z=38), \mathrm{Cs}^{+}(z=55), \mathrm{La}^{2+}(z=57), \mathrm{Pb}^{2+}(z=82), \mathrm{Yb}^{2+}(z=70)$ and $\mathrm{Fe}^{2+}(z=26)$

An urn contains 6 white and 9 black balls. Two successive draws of 4 balls are made without replacement. The probability, that the first draw gives all white balls and the second draw gives all black balls, is :

Let $A$ and $B$ be two finite sets with $m$ and $n$ elements respectively. The total number of subsets of the set $A$ is 56 more than the total number of subsets of $B$. Then the distance of the point $P(m, n)$ from the point $Q(-2,-3)$ is :

\text { If } \lim _\limits{x \rightarrow 0} \frac{3+\alpha \sin x+\beta \cos x+\log _e(1-x)}{3 \tan ^2 x}=\frac{1}{3} \text {, then } 2 \alpha-\beta \text { is equal to : }

If $2 \tan ^2 \theta-5 \sec \theta=1$ has exactly 7 solutions in the interval $\left[0, \frac{n \pi}{2}\right]$, for the least value of $n \in \mathbf{N}$, then \sum_\limits{k=1}^n \frac{k}{2^k} is equal to:

Let $g(x)=3 f\left(\frac{x}{3}\right)+f(3-x)$ and $f^{\prime \prime}(x)>0$ for all $x \in(0,3)$. If $g$ is decreasing in $(0, \alpha)$ and increasing in $(\alpha, 3)$, then $8 \alpha$ is :

Let $\mathrm{R}$ be the interior region between the lines $3 x-y+1=0$ and $x+2 y-5=0$ containing the origin. The set of all values of $a$, for which the points $\left(a^2, a+1\right)$ lie in $R$, is :

Let f(x)=\int_\limits0^x g(t) \log _{\mathrm{e}}\left(\frac{1-\mathrm{t}}{1+\mathrm{t}}\right) \mathrm{dt}, where $g$ is a continuous odd function. If $\int_{-\pi / 2}^{\pi / 2}\left(f(x)+\frac{x^2 \cos x}{1+\mathrm{e}^x}\right) \mathrm{d} x=\left(\frac{\pi}{\alpha}\right)^2-\alpha$, then $\alpha$ is equal to _________.

Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R).

Assertion (A) : The property of body, by virtue of which it tends to regain its original shape when the external force is removed, is Elasticity.

Reason (R) : The restoring force depends upon the bonded inter atomic and inter molecular force of solid.

In the light of the above statements, choose the correct answer from the options given below :

The truth table of the given circuit diagram is :

A body falling under gravity covers two points $A$ and $B$ separated by $80 \mathrm{~m}$ in $2 \mathrm{~s}$. The distance of upper point A from the starting point is _________ $\mathrm{m}$ (use $\mathrm{g}=10 \mathrm{~ms}^{-2}$).

If Rydberg's constant is $R$, the longest wavelength of radiation in Paschen series will be $\frac{\alpha}{7 R}$, where $\alpha=$ ________.

Identity the incorrect pair from the following :

Given below are two statements :

Statement (I) : Oxygen being the first member of group 16 exhibits only -2 oxidation state.

Statement (II) : Down the group 16 stability of +4 oxidation state decreases and +6 oxidation state increases.

In the light of the above statements, choose the most appropriate answer from the options given below :

Which structure of protein remains intact after coagulation of egg white on boiling?

Identify B formed in the reaction.

$\mathrm{Cl}-\left(\mathrm{CH}_2\right)_4-\mathrm{Cl} \xrightarrow{\text { excess } \mathrm{NH}_3} \mathrm{~A} \xrightarrow{\mathrm{NaOH}} \mathrm{B}+\mathrm{H}_2 \mathrm{O}+\mathrm{NaCl}$

Phenolic group can be identified by a positive:

Which among the following halide/s will not show $\mathrm{S_N 1}$ reaction:

(A) $\mathrm{H}_2 \mathrm{C}=\mathrm{CH}-\mathrm{CH}_2 \mathrm{Cl}$

(B) $\mathrm{CH}_3-\mathrm{CH}=\mathrm{CH}-\mathrm{Cl}$

(C)

(D)

Choose the most appropriate answer from the options given below :

Which of the following statements is not correct about rusting of iron?

Choose the correct option having all the elements with $\mathrm{d}^{10}$ electronic configuration from the following :

The incorrect statement regarding conformations of ethane is :

The final product A, formed in the following reaction sequence is:

The quantity which changes with temperature is :

The Spin only magnetic moment value of square planar complex $\left[\mathrm{Pt}\left(\mathrm{NH}_3\right)_2 \mathrm{Cl}\left(\mathrm{NH}_2 \mathrm{CH}_3\right)\right] \mathrm{Cl}$ is _________ B.M. (Nearest integer)

(Given atomic number for $\mathrm{Pt}=78$)

Total number of compounds with Chiral carbon atoms from following is _________.

The hydrogen electrode is dipped in a solution of $\mathrm{pH}=3$ at $25^{\circ} \mathrm{C}$. The potential of the electrode will be _________ $\times 10^{-2} \mathrm{~V}$.

$\left(\frac{2.303 \mathrm{RT}}{\mathrm{F}}=0.059 \mathrm{~V}\right)$

Volume of $3 \mathrm{M} \mathrm{~NaOH}$ (formula weight $40 \mathrm{~g} \mathrm{~mol}^{-1}$ ) which can be prepared from $84 \mathrm{~g}$ of $\mathrm{NaOH}$ is __________ $\times 10^{-1} \mathrm{dm}^3$.

Let the image of the point $(1,0,7)$ in the line $\frac{x}{1}=\frac{y-1}{2}=\frac{z-2}{3}$ be the point $(\alpha, \beta, \gamma)$. Then which one of the following points lies on the line passing through $(\alpha, \beta, \gamma)$ and making angles $\frac{2 \pi}{3}$ and $\frac{3 \pi}{4}$ with $y$-axis and $z$-axis respectively and an acute angle with $x$-axis ?

$\text { The } 20^{\text {th }} \text { term from the end of the progression } 20,19 \frac{1}{4}, 18 \frac{1}{2}, 17 \frac{3}{4}, \ldots,-129 \frac{1}{4} \text { is : }$

If $y=y(x)$ is the solution curve of the differential equation $\left(x^2-4\right) \mathrm{d} y-\left(y^2-3 y\right) \mathrm{d} x=0, x>2, y(4)=\frac{3}{2}$ and the slope of the curve is never zero, then the value of $y(10)$ equals :

The lines $\frac{x-2}{2}=\frac{y}{-2}=\frac{z-7}{16}$ and $\frac{x+3}{4}=\frac{y+2}{3}=\frac{z+2}{1}$ intersect at the point $P$. If the distance of $\mathrm{P}$ from the line $\frac{x+1}{2}=\frac{y-1}{3}=\frac{z-1}{1}$ is $l$, then $14 l^2$ is equal to __________.

If the area of the region $\left\{(x, y): 0 \leq y \leq \min \left\{2 x, 6 x-x^2\right\}\right\}$ is $\mathrm{A}$, then $12 \mathrm{~A}$ is equal to ________.

If the sum of squares of all real values of $\alpha$, for which the lines $2 x-y+3=0,6 x+3 y+1=0$ and $\alpha x+2 y-2=0$ do not form a triangle is $p$, then the greatest integer less than or equal to $p$ is _________.

A ball suspended by a thread swings in a vertical plane so that its magnitude of acceleration in the extreme position and lowest position are equal. The angle $(\theta)$ of thread deflection in the extreme position will be :

Primary side of a transformer is connected to $230 \mathrm{~V}, 50 \mathrm{~Hz}$ supply. Turns ratio of primary to secondary winding is $10: 1$. Load resistance connected to secondary side is $46 \Omega$. The power consumed in it is :

Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R).

Assertion (A) : The angular speed of the moon in its orbit about the earth is more than the angular speed of the earth in its orbit about the sun.

Reason (R) : The moon takes less time to move around the earth than the time taken by the earth to move around the sun.

In the light of the above statements, choose the most appropriate answer from the options given below :

The atomic mass of ${ }_6 \mathrm{C}^{12}$ is $12.000000 \mathrm{~u}$ and that of ${ }_6 \mathrm{C}^{13}$ is $13.003354 \mathrm{~u}$. The required energy to remove a neutron from ${ }_6 \mathrm{C}^{13}$, if mass of neutron is $1.008665 \mathrm{~u}$, will be :

During an adiabatic process, the pressure of a gas is found to be proportional to the cube of its absolute temperature. The ratio of $\frac{\mathrm{Cp}}{\mathrm{Cv}}$ for the gas is :

The equation of state of a real gas is given by $\left(\mathrm{P}+\frac{\mathrm{a}}{\mathrm{V}^2}\right)(\mathrm{V}-\mathrm{b})=\mathrm{RT}$, where $\mathrm{P}, \mathrm{V}$ and $\mathrm{T}$ are pressure, volume and temperature respectively and $\mathrm{R}$ is the universal gas constant. The dimensions of $\frac{\mathrm{a}}{\mathrm{b}^2}$ is similar to that of :

Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R).

Assertion (A) : Work done by electric field on moving a positive charge on an equipotential surface is always zero.

Reason (R) : Electric lines of forces are always perpendicular to equipotential surfaces.

In the light of the above statements, choose the most appropriate answer from the options given below :

A current of $200 \mu \mathrm{A}$ deflects the coil of a moving coil galvanometer through $60^{\circ}$. The current to cause deflection through $\frac{\pi}{10}$ radian is :

Wheatstone bridge principle is used to measure the specific resistance $\left(S_1\right)$ of given wire, having length $L$, radius $r$. If $X$ is the resistance of wire, then specific resistance is ; $S_1=X\left(\frac{\pi r^2}{L}\right)$. If the length of the wire gets doubled then the value of specific resistance will be :

A series LCR circuit with $\mathrm{L}=\frac{100}{\pi} \mathrm{mH}, \mathrm{C}=\frac{10^{-3}}{\pi} \mathrm{F}$ and $\mathrm{R}=10 \Omega$, is connected across an ac source of $220 \mathrm{~V}, 50 \mathrm{~Hz}$ supply. The power factor of the circuit would be ________.

A ring and a solid sphere roll down the same inclined plane without slipping. They start from rest. The radii of both bodies are identical and the ratio of their kinetic energies is $\frac{7}{x}$, where $x$ is _________.

The electric potential at the surface of an atomic nucleus $(z=50)$ of radius $9 \times 10^{-13} \mathrm{~cm}$ is __________ $\times 10^6 \mathrm{~V}$.

The magnetic field at the centre of a wire loop formed by two semicircular wires of radii $R_1=2 \pi \mathrm{m}$ and $R_2=4 \pi \mathrm{m}$, carrying current $\mathrm{I}=4 \mathrm{~A}$ as per figure given below is $\alpha \times 10^{-7} \mathrm{~T}$. The value of $\alpha$ is ________. (Centre $\mathrm{O}$ is common for all segments)

A parallel beam of monochromatic light of wavelength 5000 $\mathop A\limits^o$ is incident normally on a single narrow slit of width $0.001 \mathrm{~mm}$. The light is focused by convex lens on screen, placed on its focal plane. The first minima will be formed for the angle of diffraction of _________ (degree).