'A' in the above reaction is:

Given below are two statement: one is labelled as Assertion $\mathbf{A}$ and the other is labelled as Reason $\mathbf{R}$

Assertion A: $5 \mathrm{f}$ electrons can participate in bonding to a far greater extent than $4 \mathrm{f}$ electrons

Reason R: $5 \mathrm{f}$ orbitals are not as buried as $4 \mathrm{f}$ orbitals

In the light of the above statements, choose the correct answer from the options given below

A metal chloride contains $55.0 \%$ of chlorine by weight . $100 \mathrm{~mL}$ vapours of the metal chloride at STP weigh $0.57 \mathrm{~g}$. The molecular formula of the metal chloride is

(Given: Atomic mass of chlorine is $35.5 \mathrm{u}$)

The incorrect statement regarding the reaction given below is

Match List I with List II

Choose the correct answer from the options given below:

Correct statements for the given reaction are :

A. Compound '$\mathrm{B}$' is aromatic

B. The completion of above reaction is very slow

C. 'A' shows tautomerism

D. The bond lengths of C-C in compound $B$ are found to be same

Choose the correct answer from the options given below:

Given below are two statements :

Statement I : $\mathrm{SbCl}_{5}$ is more covalent than $\mathrm{SbCl}_{3}$

Statement II: The higher oxides of halogens also tend to be more stable than the lower ones.

In the light of the above statements, choose the most appropriate answer from the options given below :

The two products formed in above reaction are -

The bond order and magnetic property of acetylide ion are same as that of

For lead storage battery pick the correct statements

A. During charging of battery, $\mathrm{PbSO}_{4}$ on anode is converted into $\mathrm{PbO}_{2}$

B. During charging of battery, $\mathrm{PbSO}_{4}$ on cathode is converted into $\mathrm{PbO}_{2}$

C. Lead storage battery consists of grid of lead packed with $\mathrm{PbO}_{2}$ as anode

D. Lead storage battery has $\sim 38 \%$ solution of sulphuric acid as an electrolyte

Choose the correct answer from the options given below:

The major product 'P' formed in the following sequence of reactions is

Given below are two statements :

Statement I : Boron is extremely hard indicating its high lattice energy.

Statement II : Boron has highest melting and boiling point compared to its other group members.

In the light of the above statements, choose the most appropriate answer from the options given below :

In the following reaction

'A' is

In an oligopeptide named Alanylglycylphenyl alanyl isoleucine, the number of $\mathrm{sp}^{2}$ hybridised carbons is __________.

80 mole percent of $\mathrm{MgCl}_{2}$ is dissociated in aqueous solution. The vapour pressure of $1.0 ~\mathrm{molal}$ aqueous solution of $\mathrm{MgCl}_{2}$ at $38^{\circ} \mathrm{C}$ is ____________ $\mathrm{mm} ~\mathrm{Hg.} ~\mathrm{(Nearest} ~\mathrm{integer)}$

Given : Vapour pressure of water at $38^{\circ} \mathrm{C}$ is $50 \mathrm{~mm} ~\mathrm{Hg}$

Let $\mathrm{C}$ be the circle in the complex plane with centre $\mathrm{z}_{0}=\frac{1}{2}(1+3 i)$ and radius $r=1$. Let $\mathrm{z}_{1}=1+\mathrm{i}$ and the complex number $z_{2}$ be outside the circle $C$ such that $\left|z_{1}-z_{0}\right|\left|z_{2}-z_{0}\right|=1$. If $z_{0}, z_{1}$ and $z_{2}$ are collinear, then the smaller value of $\left|z_{2}\right|^{2}$ is equal to :

If the point $\left(\alpha, \frac{7 \sqrt{3}}{3}\right)$ lies on the curve traced by the mid-points of the line segments of the lines $x \cos \theta+y \sin \theta=7, \theta \in\left(0, \frac{\pi}{2}\right)$ between the co-ordinates axes, then $\alpha$ is equal to :

Let the digits a, b, c be in A. P. Nine-digit numbers are to be formed using each of these three digits thrice such that three consecutive digits are in A.P. at least once. How many such numbers can be formed?

Let $[x]$ be the greatest integer $\leq x$. Then the number of points in the interval $(-2,1)$, where the function $f(x)=|[x]|+\sqrt{x-[x]}$ is discontinuous, is ___________.

A particle is executing simple harmonic motion (SHM). The ratio of potential energy and kinetic energy of the particle when its displacement is half of its amplitude will be

Given below are two statements: one is labelled as Assertion $\mathbf{A}$ and the other is labelled as Reason $\mathbf{R}$

Assertion A : EM waves used for optical communication have longer wavelengths than that of microwave, employed in Radar technology.

Reason R : Infrared EM waves are more energetic than microwaves, (used in Radar)

In the light of given statements, choose the correct answer from the options given below.

The ratio of escape velocity of a planet to the escape velocity of earth will be:-

Given: Mass of the planet is 16 times mass of earth and radius of the planet is 4 times the radius of earth.

Three forces $F_{1}=10 \mathrm{~N}, F_{2}=8 \mathrm{~N}, \mathrm{~F}_{3}=6 \mathrm{~N}$ are acting on a particle of mass $5 \mathrm{~kg}$. The forces $\mathrm{F}_{2}$ and $\mathrm{F}_{3}$ are applied perpendicularly so that particle remains at rest. If the force $F_{1}$ is removed, then the acceleration of the particle is:

A $12.5 \mathrm{~eV}$ electron beam is used to bombard gaseous hydrogen at room temperature. The number of spectral lines emitted will be:

Given below are two statements:

Statement I : When the frequency of an a.c source in a series LCR circuit increases, the current in the circuit first increases, attains a maximum value and then decreases.

Statement II : In a series LCR circuit, the value of power factor at resonance is one.

In the light of given statements, choose the most appropriate answer from the options given below.

64 identical drops each charged upto potential of $10 ~\mathrm{mV}$ are combined to form a bigger drop. The potential of the bigger drop will be __________ $\mathrm{mV}$.

For a rolling spherical shell, the ratio of rotational kinetic energy and total kinetic energy is $\frac{x}{5}$. The value of $x$ is ___________.

A common example of alpha decay is ${ }_{92}^{238} \mathrm{U} \longrightarrow{ }_{90}^{234} \mathrm{Th}+{ }_{2} \mathrm{He}^{4}+\mathrm{Q}$

Given :

${ }_{92}^{238} \mathrm{U}=238.05060 ~\mathrm{u}$,

${ }_{90}^{234} \mathrm{Th}=234.04360 ~\mathrm{u}$,

${ }_{2}^{4} \mathrm{He}=4.00260 ~\mathrm{u}$ and

$1 \mathrm{u}=931.5 \frac{\mathrm{MeV}}{c^{2}}$

The energy released $(Q)$ during the alpha decay of ${ }_{92}^{238} \mathrm{U}$ is __________ MeV

Two dice A and B are rolled. Let the numbers obtained on A and B be $\alpha$ and $\beta$ respectively. If the variance of $\alpha-\beta$ is $\frac{p}{q}$, where $p$ and $q$ are co-prime, then the sum of the positive divisors of $p$ is equal to :

Let $y=y(x), y > 0$, be a solution curve of the differential equation $\left(1+x^{2}\right) \mathrm{d} y=y(x-y) \mathrm{d} x$. If $y(0)=1$ and $y(2 \sqrt{2})=\beta$, then

Let the lines $l_{1}: \frac{x+5}{3}=\frac{y+4}{1}=\frac{z-\alpha}{-2}$ and $l_{2}: 3 x+2 y+z-2=0=x-3 y+2 z-13$ be coplanar. If the point $\mathrm{P}(a, b, c)$ on $l_{1}$ is nearest to the point $\mathrm{Q}(-4,-3,2)$, then $|a|+|b|+|c|$ is equal to

Let $\alpha, \beta$ be the roots of the quadratic equation $x^{2}+\sqrt{6} x+3=0$. Then $\frac{\alpha^{23}+\beta^{23}+\alpha^{14}+\beta^{14}}{\alpha^{15}+\beta^{15}+\alpha^{10}+\beta^{10}}$ is equal to :

Let $\mathrm{P}\left(\frac{2 \sqrt{3}}{\sqrt{7}}, \frac{6}{\sqrt{7}}\right), \mathrm{Q}, \mathrm{R}$ and $\mathrm{S}$ be four points on the ellipse $9 x^{2}+4 y^{2}=36$. Let $\mathrm{PQ}$ and $\mathrm{RS}$ be mutually perpendicular and pass through the origin. If $\frac{1}{(P Q)^{2}}+\frac{1}{(R S)^{2}}=\frac{p}{q}$, where $p$ and $q$ are coprime, then $p+q$ is equal to :

Two circles in the first quadrant of radii $r_{1}$ and $r_{2}$ touch the coordinate axes. Each of them cuts off an intercept of 2 units with the line $x+y=2$. Then $r_{1}^{2}+r_{2}^{2}-r_{1} r_{2}$ is equal to ___________.

Let the positive numbers $a_{1}, a_{2}, a_{3}, a_{4}$ and $a_{5}$ be in a G.P. Let their mean and variance be $\frac{31}{10}$ and $\frac{m}{n}$ respectively, where $m$ and $n$ are co-prime. If the mean of their reciprocals is $\frac{31}{40}$ and $a_{3}+a_{4}+a_{5}=14$, then $m+n$ is equal to ___________.

Two satellites $\mathrm{A}$ and $\mathrm{B}$ move round the earth in the same orbit. The mass of $\mathrm{A}$ is twice the mass of $\mathrm{B}$. The quantity which is same for the two satellites will be

An ice cube has a bubble inside. When viewed from one side the apparent distance of the bubble is $12 \mathrm{~cm}$. When viewed from the opposite side, the apparent distance of the bubble is observed as $4 \mathrm{~cm}$. If the side of the ice cube is $24 \mathrm{~cm}$, the refractive index of the ice cube is

A wire of resistance $160 ~\Omega$ is melted and drawn in a wire of one-fourth of its length. The new resistance of the wire will be

The current flowing through a conductor connected across a source is $2 \mathrm{~A}$ and 1.2 $\mathrm{A}$ at $0^{\circ} \mathrm{C}$ and $100^{\circ} \mathrm{C}$ respectively. The current flowing through the conductor at $50^{\circ} \mathrm{C}$ will be ___________ $\times 10^{2} \mathrm{~mA}$.

A conducting circular loop is placed in a uniform magnetic field of $0.4 \mathrm{~T}$ with its plane perpendicular to the field. Somehow, the radius of the loop starts expanding at a constant rate of $1 \mathrm{~mm} / \mathrm{s}$. The magnitude of induced emf in the loop at an instant when the radius of the loop is $2 \mathrm{~cm}$ will be ___________ $\mu \mathrm{V}$.

Values of work function (W$_0$) for a few metals are given below

The number of metals which will show photoelectric effect when light of wavelength $400 \mathrm{~nm}$ falls on it is ___________

Given: $\mathrm{h}=6.6 \times 10^{-34} \mathrm{~J} \mathrm{~s}$

$c=3 \times 10^{8} \mathrm{~ms}^{-1}$

$e=1.6 \times 10^{-19} \mathrm{C}$

The reaction $2 \mathrm{NO}+\mathrm{Br}_{2} \rightarrow 2 \mathrm{NOBr}$

takes places through the mechanism given below:

$\mathrm{NO}+\mathrm{Br}_{2} \Leftrightarrow \mathrm{NOBr}_{2}$ (fast)

$\mathrm{NOBr}_{2}+\mathrm{NO} \rightarrow 2 \mathrm{NOBr}$ (slow)

The overall order of the reaction is ___________.

An analyst wants to convert $1 \mathrm{~L} \mathrm{~HCl}$ of $\mathrm{pH}=1$ to a solution of $\mathrm{HCl}$ of $\mathrm{pH} ~2$. The volume of water needed to do this dilution is __________ $\mathrm{mL}$. (Nearest integer)

One mole of an ideal gas at $350 \mathrm{~K}$ is in a $2.0 \mathrm{~L}$ vessel of thermally conducting walls, which are in contact with the surroundings. It undergoes isothermal reversible expansion from 2.0 L to $3.0 \mathrm{~L}$ against a constant pressure of $4 \mathrm{~atm}$. The change in entropy of the surroundings ( $\Delta \mathrm{S})$ is ___________ $\mathrm{J} \mathrm{K}^{-1}$ (Nearest integer)

Given: $\mathrm{R}=8.314 \mathrm{~J} \mathrm{~K}^{-1} \mathrm{~mol}^{-1}$.

If the local maximum value of the function $f(x)=\left(\frac{\sqrt{3 e}}{2 \sin x}\right)^{\sin ^{2} x}, x \in\left(0, \frac{\pi}{2}\right)$ , is $\frac{k}{e}$, then $\left(\frac{k}{e}\right)^{8}+\frac{k^{8}}{e^{5}}+k^{8}$ is equal to

The area of the region enclosed by the curve $y=x^{3}$ and its tangent at the point $(-1,-1)$ is :

The number of relations, on the set $\{1,2,3\}$ containing $(1,2)$ and $(2,3)$, which are reflexive and transitive but not symmetric, is __________.

Let $I(x)=\int \sqrt{\frac{x+7}{x}} \mathrm{~d} x$ and $I(9)=12+7 \log _{e} 7$. If $I(1)=\alpha+7 \log _{e}(1+2 \sqrt{2})$, then $\alpha^{4}$ is equal to _________.

Given below are two statements:

Statement I : A truck and a car moving with same kinetic energy are brought to rest by applying breaks which provide equal retarding forces. Both come to rest in equal distance.

Statement II : A car moving towards east takes a turn and moves towards north, the speed remains unchanged. The acceleration of the car is zero.

In the light of given statements, choose the most appropriate answer from the options given below

Match List I with List II

Choose the correct answer from the options given below:

A proton and an $\alpha$-particle are accelerated from rest by $2 \mathrm{~V}$ and $4 \mathrm{~V}$ potentials, respectively. The ratio of their de-Broglie wavelength is :

Given below are two statements:

Statement I : The diamagnetic property depends on temperature.

Statement II : The induced magnetic dipole moment in a diamagnetic sample is always opposite to the magnetizing field.

In the light of given statements, choose the correct answer from the options given below.

If the r. m.s speed of chlorine molecule is $490 \mathrm{~m} / \mathrm{s}$ at $27^{\circ} \mathrm{C}$, the r. m. s speed of argon molecules at the same temperature will be (Atomic mass of argon $=39.9 \mathrm{u}$, molecular mass of chlorine $=70.9 \mathrm{u}$ )

To maintain a speed of 80 km/h by a bus of mass 500 kg on a plane rough road for 4 km distance, the work done by the engine of the bus will be ____________ KJ. [The coefficient of friction between tyre of bus and road is 0.04.]

Two convex lenses of focal length $20 \mathrm{~cm}$ each are placed coaxially with a separation of $60 \mathrm{~cm}$ between them. The image of the distant object formed by the combination is at _____________ $\mathrm{cm}$ from the first lens.

For a certain organ pipe, the first three resonance frequencies are in the ratio of $1:3:5$ respectively. If the frequency of fifth harmonic is $405 \mathrm{~Hz}$ and the speed of sound in air is $324 \mathrm{~ms}^{-1}$ the length of the organ pipe is _________ $\mathrm{m}$.

Three organic compounds A, B and $\mathrm{C}$ were allowed to run in thin layer chromatography using hexane and gave the following result (see figure). The $\mathrm{R}_{\mathrm{f}}$ value of the most polar compound is ____________ $\times 10^{-2}$

The value of $x$ in compound 'D' is _________.

The mass of NH$_3$ produced when 131.8 kg of cyclohexanecarbaldehyde undergoes Tollen's test is ________ kg. (Nearest Integer)

Molar Mass of

C = 12g/mol

N = 14g/mol

O = 16g/mol

Let $A=\left[\begin{array}{cc}1 & \frac{1}{51} \\ 0 & 1\end{array}\right]$. If $\mathrm{B}=\left[\begin{array}{cc}1 & 2 \\ -1 & -1\end{array}\right] A\left[\begin{array}{cc}-1 & -2 \\ 1 & 1\end{array}\right]$, then the sum of all the elements of the matrix \sum_\limits{n=1}^{50} B^{n} is equal to

The number of five digit numbers, greater than 40000 and divisible by 5 , which can be formed using the digits $0,1,3,5,7$ and 9 without repetition, is equal to :

Let $\mathrm{D}$ be the domain of the function $f(x)=\sin ^{-1}\left(\log _{3 x}\left(\frac{6+2 \log _{3} x}{-5 x}\right)\right)$. If the range of the function $\mathrm{g}: \mathrm{D} \rightarrow \mathbb{R}$ defined by $\mathrm{g}(x)=x-[x],([x]$ is the greatest integer function), is $(\alpha, \beta)$, then $\alpha^{2}+\frac{5}{\beta}$ is equal to

Let \mathrm{D}_{\mathrm{k}}=\left|\begin{array}{ccc}1 & 2 k & 2 k-1 \\ n & n^{2}+n+2 & n^{2} \\ n & n^{2}+n & n^{2}+n+2\end{array}\right|\(. If \)\sum_\limits{k=1}^{n} \mathrm{D}_{\mathrm{k}}=96\(, then \)n is equal to _____________.

A fair $n(n > 1)$ faces die is rolled repeatedly until a number less than $n$ appears. If the mean of the number of tosses required is $\frac{n}{9}$, then $n$ is equal to ____________.

If \int_\limits{-0.15}^{0.15}\left|100 x^{2}-1\right| d x=\frac{k}{3000}, then $k$ is equal to ___________.

Given below are two statements: one is labelled as Assertion A and the other is labelled as Reason R

Assertion A : If an electric dipole of dipole moment $30 \times 10^{-5} ~\mathrm{C} ~\mathrm{m}$ is enclosed by a closed surface, the net flux coming out of the surface will be zero.

Reason R : Electric dipole consists of two equal and opposite charges.

In the light of above, statements, choose the correct answer from the options given below.

A ball is thrown vertically upward with an initial velocity of $150 \mathrm{~m} / \mathrm{s}$. The ratio of velocity after $3 \mathrm{~s}$ and $5 \mathrm{~s}$ is $\frac{x+1}{x}$. The value of $x$ is ___________.

$\left\{\right.$ take, $\left.g=10 \mathrm{~m} / \mathrm{s}^{2}\right\}$

Glycerin of density $1.25 \times 10^{3} \mathrm{~kg} \mathrm{~m}^{-3}$ is flowing through the conical section of pipe The area of cross-section of the pipe at its ends are $10 \mathrm{~cm}^{2}$ and $5 \mathrm{~cm}^{2}$ and pressure drop across its length is $3 ~\mathrm{Nm}^{-2}$. The rate of flow of glycerin through the pipe is $x \times 10^{-5} \mathrm{~m}^{3} \mathrm{~s}^{-1}$. The value of $x$ is ___________.