$\mathrm{O}-\mathrm{O}$ bond length in $\mathrm{H}_{2} \mathrm{O}_{2}$ is $\underline{\mathrm{X}}$ than the $\mathrm{O}-\mathrm{O}$ bond length in $\mathrm{F}_{2} \mathrm{O}_{2}$. The $\mathrm{O}-\mathrm{H}$ bond length in $\mathrm{H}_{2} \mathrm{O}_{2}$ is $\underline{Y}$ than that of the $\mathrm{O}-\mathrm{F}$ bond in $\mathrm{F}_{2} \mathrm{O}_{2}$.

Choose the correct option for $\underline{X}$ and $\underline{Y}$ from those given below :

All structures given below are of vitamin C. Most stable of them is :

'$\mathrm{X}$' is :

In a reaction,

reagents 'X' and 'Y' respectively are :

Given below are two statements :

Statement I : Sulphanilic acid gives esterification test for carboxyl group.

Statement II : Sulphanilic acid gives red colour in Lassigne's test for extra element detection.

In the light of the above statements, choose the most appropriate answer from the options given below :

Which element is not present in Nessler's reagent?

Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R).

Assertion (A) : $\alpha$-halocarboxylic acid on reaction with dil. $\mathrm{NH_3}$ gives good yield of $\alpha$-amino carboxylic acid whereas the yield of amines is very low when prepared from alkyl halides.

Reason (R) : Amino acids exist in zwitter ion form in aqueous medium.

In the light of the above statements, choose the correct answer from the options given below :

Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R).

Assertion (A) : $\mathrm{Cu^{2+}}$ in water is more stable than $\mathrm{Cu^{+}}$.

Reason (R) : Enthalpy of hydration for $\mathrm{Cu^{2+}}$ is much less than that of $\mathrm{Cu^{+}}$.

In the light of the above statements, choose the correct answer from the options given below :

The effect of addition of helium gas to the following reaction in equilibrium state, is :

$\mathrm{PCl}_{5}(\mathrm{g}) \rightleftharpoons \mathrm{PCl}_{3}(\mathrm{g})+\mathrm{Cl}_{2}(\mathrm{g})$

Which one of the following sets of ions represents a collection of isoelectronic species?

(Given : Atomic Number : $\mathrm{F:9,Cl:17,Na=11,Mg=12,Al=13,K=19,Ca=20,Sc=21}$)

For electron gain enthalpies of the elements denoted as $\Delta_{\mathrm{eg}} \mathrm{H}$, the incorrect option is :

Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R)

Assertion (A) : An aqueous solution of $\mathrm{KOH}$ when used for volumetric analysis, its concentration should be checked before the use.

Reason (R) : On aging, $\mathrm{KOH}$ solution absorbs atmospheric $\mathrm{CO}_{2}$.

In the light of the above statements, choose the correct answer from the options given below :

The complex cation which has two isomers is :

The structures of major products A, B and C in the following reaction are sequence.

The graph which represents the following reaction is :

Among following compounds, the number of those present in copper matte is ___________.

A. $\mathrm{CuCO_{3}}$

B. $\mathrm{Cu_{2}S}$

C. $\mathrm{Cu_{2}O}$

D. $\mathrm{FeO}$

$1 \times 10^{-5} ~\mathrm{M} ~\mathrm{AgNO}_{3}$ is added to $1 \mathrm{~L}$ of saturated solution of $\mathrm{AgBr}$. The conductivity of this solution at $298 \mathrm{~K}$ is _____________ $\times 10^{-8} \mathrm{~S} \mathrm{~m}^{-1}$.

[Given : $\mathrm{K}_{\mathrm{SP}}(\mathrm{AgBr})=4.9 \times 10^{-13}$ at $298 \mathrm{~K}$

$$\begin{aligned} & \lambda_{\mathrm{Ag}^{+}}^{0}=6 \times 10^{-3} \mathrm{~S} \mathrm{~m}^{2} \mathrm{~mol}^{-1} \\ & \lambda_{\mathrm{Br}^{-}}^{0}=8 \times 10^{-3} \mathrm{~S} \mathrm{~m}^{2} \mathrm{~mol}^{-1} \\ & \left.\lambda_{\mathrm{NO}_{3}^{-}}^{0}=7 \times 10^{-3} \mathrm{~S} \mathrm{~m}^{2} \mathrm{~mol}^{-1}\right] \end{aligned}$$

Testosterone, which is a steroidal hormone, has the following structure.

The total number of asymmetric carbon atom/s in testosterone is ____________.

$20 \%$ of acetic acid is dissociated when its $5 \mathrm{~g}$ is added to $500 \mathrm{~mL}$ of water. The depression in freezing point of such water is _________ $\times 10^{-3}{ }^{\circ} \mathrm{C}$.

Atomic mass of $\mathrm{C}, \mathrm{H}$ and $\mathrm{O}$ are 12,1 and 16 a.m.u. respectively.

[Given : Molal depression constant and density of water are $1.86 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}$ and $1 \mathrm{~g} \mathrm{~cm}^{-3}$ respectively.]

$0.3 \mathrm{~g}$ of ethane undergoes combustion at $27^{\circ} \mathrm{C}$ in a bomb calorimeter. The temperature of calorimeter system (including the water) is found to rise by $0.5^{\circ} \mathrm{C}$. The heat evolved during combustion of ethane at constant pressure is ____________ $\mathrm{kJ} ~\mathrm{mol}{ }^{-1}$. (Nearest integer)

[Given : The heat capacity of the calorimeter system is $20 \mathrm{~kJ} \mathrm{~K}^{-1}, \mathrm{R}=8.3 ~\mathrm{JK}^{-1} \mathrm{~mol}^{-1}$.

Assume ideal gas behaviour.

Atomic mass of $\mathrm{C}$ and $\mathrm{H}$ are 12 and $1 \mathrm{~g} \mathrm{~mol}^{-1}$ respectively]

The molality of a $10 \%(\mathrm{v} / \mathrm{v})$ solution of di-bromine solution in $\mathrm{CCl}_{4}$ (carbon tetrachloride) is '$x$'. $x=$ ____________ $\times 10^{-2} ~\mathrm{M}$. (Nearest integer)

[Given : molar mass of $\mathrm{Br}_{2}=160 \mathrm{~g} \mathrm{~mol}^{-1}$

atomic mass of $\mathrm{C}=12 \mathrm{~g} \mathrm{~mol}^{-1}$

atomic mass of $\mathrm{Cl}=35.5 \mathrm{~g} \mathrm{~mol}^{-1}$

density of dibromine $=3.2 \mathrm{~g} \mathrm{~cm}^{-3}$

density of $\mathrm{CCl}_{4}=1.6 \mathrm{~g} \mathrm{~cm}^{-3}$]

The spin only magnetic moment of $\left[\mathrm{Mn}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]^{2+}$ complexes is _________ B.M. (Nearest integer)

(Given : Atomic no. of Mn is 25)

$\mathrm{A}$ $\rightarrow \mathrm{B}$

The above reaction is of zero order. Half life of this reaction is $50 \mathrm{~min}$. The time taken for the concentration of $\mathrm{A}$ to reduce to one-fourth of its initial value is ____________ min. (Nearest integer)

Let $9=x_{1} < x_{2} < \ldots < x_{7}$ be in an A.P. with common difference d. If the standard deviation of $x_{1}, x_{2}..., x_{7}$ is 4 and the mean is $\bar{x}$, then $\bar{x}+x_{6}$ is equal to :

Let $P(S)$ denote the power set of $S=\{1,2,3, \ldots ., 10\}$. Define the relations $R_{1}$ and $R_{2}$ on $P(S)$ as $\mathrm{AR}_{1} \mathrm{~B}$ if $\left(\mathrm{A} \cap \mathrm{B}^{\mathrm{c}}\right) \cup\left(\mathrm{B} \cap \mathrm{A}^{\mathrm{c}}\right)=\emptyset$ and $\mathrm{AR}_{2} \mathrm{~B}$ if $\mathrm{A} \cup \mathrm{B}^{\mathrm{c}}=\mathrm{B} \cup \mathrm{A}^{\mathrm{c}}, \forall \mathrm{A}, \mathrm{B} \in \mathrm{P}(\mathrm{S})$. Then :

The sum of the absolute maximum and minimum values of the function $f(x)=\left|x^{2}-5 x+6\right|-3 x+2$ in the interval $[-1,3]$ is equal to :

Let $\vec{a}=5 \hat{i}-\hat{j}-3 \hat{k}$ and $\vec{b}=\hat{i}+3 \hat{j}+5 \hat{k}$ be two vectors. Then which one of the following statements is TRUE ?

For the system of linear equations $\alpha x+y+z=1,x+\alpha y+z=1,x+y+\alpha z=\beta$, which one of the following statements is NOT correct?

If $y(x)=x^{x},x > 0$, then $y''(2)-2y'(2)$ is equal to

The value of the integral

$\int\limits_{ - {\pi \over 4}}^{{\pi \over 4}} {{{x + {\pi \over 4}} \over {2 - \cos 2x}}dx}$ is :

The area of the region given by $\{ (x,y):xy \le 8,1 \le y \le {x^2}\}$ is :

The number of integral values of k, for which one root of the equation $2x^2-8x+k=0$ lies in the interval (1, 2) and its other root lies in the interval (2, 3), is :

Let $a,b$ be two real numbers such that $ab < 0$. IF the complex number $\frac{1+ai}{b+i}$ is of unit modulus and $a+ib$ lies on the circle $|z-1|=|2z|$, then a possible value of $\frac{1+[a]}{4b}$, where $[t]$ is greatest integer function, is :

If A = {1 \over 2}\left[ {\matrix{ 1 & {\sqrt 3 } \cr { - \sqrt 3 } & 1 \cr } } \right], then :

Two dice are thrown independently. Let $\mathrm{A}$ be the event that the number appeared on the $1^{\text {st }}$ die is less than the number appeared on the $2^{\text {nd }}$ die, $\mathrm{B}$ be the event that the number appeared on the $1^{\text {st }}$ die is even and that on the second die is odd, and $\mathrm{C}$ be the event that the number appeared on the $1^{\text {st }}$ die is odd and that on the $2^{\text {nd }}$ is even. Then :

Let $\vec{a}=2 \hat{i}-7 \hat{j}+5 \hat{k}, \vec{b}=\hat{i}+\hat{k}$ and $\vec{c}=\hat{i}+2 \hat{j}-3 \hat{k}$ be three given vectors. If $\overrightarrow{\mathrm{r}}$ is a vector such that $\vec{r} \times \vec{a}=\vec{c} \times \vec{a}$ and $\vec{r} \cdot \vec{b}=0$, then $|\vec{r}|$ is equal to :

Let $S = \left\{ {x \in R:0 < x < 1\,\mathrm{and}\,2{{\tan }^{ - 1}}\left( {{{1 - x} \over {1 + x}}} \right) = {{\cos }^{ - 1}}\left( {{{1 - {x^2}} \over {1 + {x^2}}}} \right)} \right\}$.

If $\mathrm{n(S)}$ denotes the number of elements in $\mathrm{S}$ then :

Let $f:\mathbb{R}-{0,1}\to \mathbb{R}$ be a function such that $f(x)+f\left(\frac{1}{1-x}\right)=1+x$. Then $f(2)$ is equal to

Let $\alpha x=\exp \left(x^{\beta} y^{\gamma}\right)$ be the solution of the differential equation $2 x^{2} y \mathrm{~d} y-\left(1-x y^{2}\right) \mathrm{d} x=0, x > 0,y(2)=\sqrt{\log _{e} 2}$. Then $\alpha+\beta-\gamma$ equals :

If the $x$-intercept of a focal chord of the parabola $y^{2}=8x+4y+4$ is 3, then the length of this chord is equal to ____________.

If $\int\limits_0^\pi {{{{5^{\cos x}}(1 + \cos x\cos 3x + {{\cos }^2}x + {{\cos }^3}x\cos 3x)dx} \over {1 + {5^{\cos x}}}} = {{k\pi } \over {16}}}$, then k is equal to _____________.

Let the sixth term in the binomial expansion of {\left( {\sqrt {{2^{{{\log }_2}\left( {10 - {3^x}} \right)}}} + \root 5 \of {{2^{(x - 2){{\log }_2}3}}} } \right)^m} in the increasing powers of $2^{(x-2) \log _{2} 3}$, be 21 . If the binomial coefficients of the second, third and fourth terms in the expansion are respectively the first, third and fifth terms of an A.P., then the sum of the squares of all possible values of $x$ is __________.

The sum of the common terms of the following three arithmetic progressions.

$3,7,11,15, \ldots ., 399$,

$2,5,8,11, \ldots ., 359$ and

$2,7,12,17, \ldots ., 197$,

is equal to _____________.

Number of integral solutions to the equation $x+y+z=21$, where $x \ge 1,y\ge3,z\ge4$, is equal to ____________.

If the term without $x$ in the expansion of $\left(x^{\frac{2}{3}}+\frac{\alpha}{x^{3}}\right)^{22}$ is 7315 , then $|\alpha|$ is equal to ___________.

The total number of six digit numbers, formed using the digits 4, 5, 9 only and divisible by 6, is ____________.

Given below are two statements : One is labelled as Assertion $\mathbf{A}$ and the other is labelled as Reason $\mathbf{R}$.

Assertion A : For measuring the potential difference across a resistance of $600 \Omega$, the voltmeter with resistance $1000 \Omega$ will be preferred over voltmeter with resistance $4000 \Omega$.

Reason R : Voltmeter with higher resistance will draw smaller current than voltmeter with lower resistance.

In the light of the above statements, choose the most appropriate answer from the options given below.

The escape velocities of two planets $\mathrm{A}$ and $\mathrm{B}$ are in the ratio $1: 2$. If the ratio of their radii respectively is $1: 3$, then the ratio of acceleration due to gravity of planet A to the acceleration of gravity of planet B will be :

The ratio of average electric energy density and total average energy density of electromagnetic wave is :

Equivalent resistance between the adjacent corners of a regular n-sided polygon of uniform wire of resistance R would be :

A coil is placed in magnetic field such that plane of coil is perpendicular to the direction of magnetic field. The magnetic flux through a coil can be changed :

A. By changing the magnitude of the magnetic field within the coil.

B. By changing the area of coil within the magnetic field.

C. By changing the angle between the direction of magnetic field and the plane of the coil.

D. By reversing the magnetic field direction abruptly without changing its magnitude.

Choose the most appropriate answer from the options given below :

Given below are two statements: One is labeled as Assertion A and the other is labeled as Reason R.

Assertion A : Two metallic spheres are charged to the same potential. One of them is hollow and another is solid, and both have the same radii. Solid sphere will have lower charge than the hollow one.

Reason R : Capacitance of metallic spheres depend on the radii of spheres

In light of the above statements, choose the correct answer from the options given below.

Choose the correct length (L) versus square of the time period ($\mathrm{T}^{2}$) graph for a simple pendulum executing simple harmonic motion.

If the velocity of light $\mathrm{c}$, universal gravitational constant $\mathrm{G}$ and Planck's constant $\mathrm{h}$ are chosen as fundamental quantities. The dimensions of mass in the new system is :

The Young's modulus of a steel wire of length $6 \mathrm{~m}$ and cross-sectional area $3 \mathrm{~mm}^{2}$, is $2 \times 10^{11}~\mathrm{N} / \mathrm{m}^{2}$. The wire is suspended from its support on a given planet. A block of mass $4 \mathrm{~kg}$ is attached to the free end of the wire. The acceleration due to gravity on the planet is $\frac{1}{4}$ of its value on the earth. The elongation of wire is (Take $g$ on the earth $=10 \mathrm{~m} / \mathrm{s}^{2}$) :

Choose the correct statement about Zener diode :

As shown in the figure a block of mass 10 kg lying on a horizontal surface is pulled by a force F acting at an angle $30^\circ$, with horizontal. For $\mu_s=0.25$, the block will just start to move for the value of F : [Given $g=10~\mathrm{ms}^{-2}$]

Two objects A and B are placed at 15 cm and 25 cm from the pole in front of a concave mirror having radius of curvature 40 cm. The distance between images formed by the mirror is _______________.

For a body projected at an angle with the horizontal from the ground, choose the correct statement.

As shown in the figure, a long straight conductor with semicircular arc of radius $\frac{\pi}{10}$m is carrying current $\mathrm{I=3A}$. The magnitude of the magnetic field, at the center O of the arc is :

(The permeability of the vacuum $=4\pi\times10^{-7}~\mathrm{NA}^{-2}$)

The threshold frequency of a metal is $f_{0}$. When the light of frequency $2 f_{0}$ is incident on the metal plate, the maximum velocity of photoelectrons is $v_{1}$. When the frequency of incident radiation is increased to $5 \mathrm{f}_{0}$, the maximum velocity of photoelectrons emitted is $v_{2}$. The ratio of $v_{1}$ to $v_{2}$ is :

For three low density gases A, B, C pressure versus temperature graphs are plotted while keeping them at constant volume, as shown in the figure.

The temperature corresponding to the point '$\mathrm{K}$' is :

Figures (a), (b), (c) and (d) show variation of force with time.

The impulse is highest in figure.

An electron of a hydrogen like atom, having $Z=4$, jumps from $4^{\text {th }}$ energy state to $2^{\text {nd }}$ energy state. The energy released in this process, will be :

(Given Rch = $13.6~\mathrm{eV}$)

Where R = Rydberg constant

c = Speed of light in vacuum

h = Planck's constant

A square shaped coil of area $70 \mathrm{~cm}^{2}$ having 600 turns rotates in a magnetic field of $0.4 ~\mathrm{wbm}^{-2}$, about an axis which is parallel to one of the side of the coil and perpendicular to the direction of field. If the coil completes 500 revolution in a minute, the instantaneous emf when the plane of the coil is inclined at $60^{\circ}$ with the field, will be ____________ V. (Take $\pi=\frac{22}{7}$)

A block is fastened to a horizontal spring. The block is pulled to a distance $x=10 \mathrm{~cm}$ from its equilibrium position (at $x=0$) on a frictionless surface from rest. The energy of the block at $x=5$ $\mathrm{cm}$ is $0.25 \mathrm{~J}$. The spring constant of the spring is ___________ $\mathrm{Nm}^{-1}$

As shown in the figure, in Young's double slit experiment, a thin plate of thickness $t=10 \mu \mathrm{m}$ and refractive index $\mu=1.2$ is inserted infront of slit $S_{1}$. The experiment is conducted in air $(\mu=1)$ and uses a monochromatic light of wavelength $\lambda=500 \mathrm{~nm}$. Due to the insertion of the plate, central maxima is shifted by a distance of $x \beta_{0} . \beta_{0}$ is the fringe-width befor the insertion of the plate. The value of the $x$ is _____________.

Nucleus A having $Z=17$ and equal number of protons and neutrons has $1.2 ~\mathrm{MeV}$ binding energy per nucleon.

Another nucleus $\mathrm{B}$ of $Z=12$ has total 26 nucleons and $1.8 ~\mathrm{MeV}$ binding energy per nucleons.

The difference of binding energy of $\mathrm{B}$ and $\mathrm{A}$ will be _____________ $\mathrm{MeV}$.

Moment of inertia of a disc of mass '$M$' and radius '$R$' about any of its diameter is $\frac{M R^{2}}{4}$. The moment of inertia of this disc about an axis normal to the disc and passing through a point on its edge will be, $\frac{x}{2}$ MR$^{2}$. The value of $x$ is ___________.

The surface of water in a water tank of cross section area $750 \mathrm{~cm}^{2}$ on the top of a house is $h \mathrm{~m}$ above the tap level. The speed of water coming out through the tap of cross section area $500 \mathrm{~mm}^{2}$ is $30 \mathrm{~cm} / \mathrm{s}$. At that instant, $\frac{d h}{d t}$ is $x \times 10^{-3} \mathrm{~m} / \mathrm{s}$. The value of $x$ will be ____________.

A force $\mathrm{F}=\left(5+3 y^{2}\right)$ acts on a particle in the $y$-direction, where $\mathrm{F}$ is in newton and $y$ is in meter. The work done by the force during a displacement from $y=2 \mathrm{~m}$ to $y=5 \mathrm{~m}$ is ___________ J.

For a train engine moving with speed of $20 \mathrm{~ms}^{-1}$, the driver must apply brakes at a distance of 500 $\mathrm{m}$ before the station for the train to come to rest at the station. If the brakes were applied at half of this distance, the train engine would cross the station with speed $\sqrt{x} \mathrm{~ms}^{-1}$. The value of $x$ is ____________.

(Assuming same retardation is produced by brakes)

In the given circuit, the value of $\left| {{{{\mathrm{I_1}} + {\mathrm{I_3}}} \over {{\mathrm{I_2}}}}} \right|$ is _____________

A cubical volume is bounded by the surfaces $\mathrm{x}=0, x=\mathrm{a}, y=0, y=\mathrm{a}, \mathrm{z}=0, z=\mathrm{a}$. The electric field in the region is given by $\overrightarrow{\mathrm{E}}=\mathrm{E}_{0} x \hat{i}$. Where $\mathrm{E}_{0}=4 \times 10^{4} ~\mathrm{NC}^{-1} \mathrm{~m}^{-1}$. If $\mathrm{a}=2 \mathrm{~cm}$, the charge contained in the cubical volume is $\mathrm{Q} \times 10^{-14} \mathrm{C}$. The value of $\mathrm{Q}$ is ________________.

(Take $\epsilon_{0}=9 \times 10^{-12} ~\mathrm{C}^{2} / \mathrm{Nm}^{2}$)