Given below are two statements :

Statement I : The decrease in first ionization enthalpy from B to Al is much larger than that from Al to Ga.

Statement II : The d orbitals in Ga are completely filled.

In the light of the above statements, choose the most appropriate answer from the options given below

Given below are two statements :

Statement I : Nickel is being used as the catalyst for producing syn gas and edible fats.

Statement II : Silicon forms both electron rich and electron deficient hydrides.

In the light of the above statements, choose the most appropriate answer from the options given below :

Which of the following relations are correct?

(A) $\mathrm{\Delta U=q+p\Delta V}$

(B) $\mathrm{\Delta G=\Delta H-T\Delta S}$

(C) $\Delta \mathrm{S}=\frac{q_{rev}}{T}$

(D) $\mathrm{\Delta H=\Delta U-\Delta nRT}$

Choose the most appropriate answer from the options given below :

A solution of $\mathrm{Cr O_5}$ in amyl alcohol has a __________ colour.

According to MO theory the bond orders for $\mathrm{O}$$_2^{2 - }$, $\mathrm{CO}$ and $\mathrm{NO^+}$ respectively, are

When a hydrocarbon A undergoes combustion in the presence of air, it requires 9.5 equivalents of oxygen and produces 3 equivalents of water. What is the molecular formula of A?

The set of correct statements is :

(i) Manganese exhibits +7 oxidation state in its oxide.

(ii) Ruthenium and Osmium exhibit +8 oxidation in their oxides.

(iii) Sc shows +4 oxidation state which is oxidizing in nature.

(iv) Cr shows oxidising nature in +6 oxidation state.

Correct order of spin only magnetic moment of the following complex ions is :

(Given At.no. Fe : 26, Co : 27)

Reaction of propanamide with $\mathrm{Br_2/KOH(aq)}$ produces :

(F, L, D, Y, I, Q, P are one letter codes for amino acids)

Match List I with List II

Choose the correct answer from the options given below :

The one giving maximum number of isomeric alkenes on dehydrohalogenation reaction is (excluding rearrangement)

An indicator 'X' is used for studying the effect of variation in concentration of iodide on the rate of reaction of iodide ion with $\mathrm{H_2O_2}$ at room temp. The indicator 'X' forms blue coloured complex with compound 'A' present in the solution. The indicator 'X' and compound 'A' respectively are :

Find out the major product for the following reaction.

Find out the major products from the following reaction sequence.

The volume of HCl, containing 73 g L$^{-1}$, required to completely neutralise NaOH obtained by reacting 0.69 g of metallic sodium with water, is __________ mL. (Nearest Integer)

(Given : molar masses of Na, Cl, O, H, are 23, 35.5, 16 and 1 g mol$^{-1}$ respectively.)

The equilibrium constant for the reaction

$\mathrm{Zn(s)+Sn^{2+}(aq)}$ $\rightleftharpoons$ $\mathrm{Zn^{2+}(aq)+Sn(s)}$ is $1\times10^{20}$ at 298 K. The magnitude of standard electrode potential of $\mathrm{Sn/Sn^{2+}}$ if $\mathrm{E_{Z{n^{2 + }}/Zn}^\Theta = - 0.76~V}$ is __________ $\times 10^{-2}$ V. (Nearest integer)

Given : $\mathrm{\frac{2.303RT}{F}=0.059~V}$

At 298 K

$\mathrm{N_2~(g)+3H_2~(g)\rightleftharpoons~2NH_3~(g),~K_1=4\times10^5}$

$\mathrm{N_2~(g)+O_2~(g)\rightleftharpoons~2NO~(g),~K_2=1.6\times10^{12}}$

$\mathrm{H_2~(g)+\frac{1}{2}O_2~(g)\rightleftharpoons~H_2O~(g),~K_3=1.0\times10^{-13}}$

Based on above equilibria, then equilibrium constant of the reaction, $\mathrm{2NH_3(g)+\frac{5}{2}O_2~(g)\rightleftharpoons~2NO~(g)+3H_2O~(g)}$ is ____________ $\times10^{-33}$ (Nearest integer).

The denticity of the ligand present in the Fehling's reagent is ___________.

When 0.01 mol of an organic compound containing 60% carbon was burnt completely, 4.4 g of CO$_2$ was produced. The molar mass of compound is _____________ g mol$^{-1}$ (Nearest integer).

Total number of acidic oxides among

$\mathrm{N_2O_3,NO_2,N_2O,Cl_2O_7,SO_2,CO,CaO,Na_2O}$ and $\mathrm{NO}$ is ____________.

Assume that the radius of the first Bohr orbit of hydrogen atom is 0.6 $\mathrm{\mathop A\limits^o }$. The radius of the third Bohr orbit of He$^+$ is __________ picometer. (Nearest Integer)

For conversion of compound A $\to$ B, the rate constant of the reaction was found to be $\mathrm{4.6\times10^{-5}~L~mol^{-1}~s^{-1}}$. The order of the reaction is ____________.

Let $y=y(x)$ be the solution of the differential equation $x{\log _e}x{{dy} \over {dx}} + y = {x^2}{\log _e}x,(x > 1)$. If $y(2) = 2$, then $y(e)$ is equal to

Let R be a relation defined on $\mathbb{N}$ as $a\mathrm{R}b$ if $2a+3b$ is a multiple of $5,a,b\in \mathbb{N}$. Then R is

The letters of the word OUGHT are written in all possible ways and these words are arranged as in a dictionary, in a series. Then the serial number of the word TOUGH is :

If $\overrightarrow a = \widehat i + 2\widehat k,\overrightarrow b = \widehat i + \widehat j + \widehat k,\overrightarrow c = 7\widehat i - 3\widehat j + 4\widehat k,\overrightarrow r \times \overrightarrow b + \overrightarrow b \times \overrightarrow c = \overrightarrow 0$ and $\overrightarrow r \,.\,\overrightarrow a = 0$. Then $\overrightarrow r \,.\,\overrightarrow c$ is equal to :

The number of 3 digit numbers, that are divisible by either 3 or 4 but not divisible by 48, is :

Let $\mathrm{S} = \{ {w_1},{w_2},......\}$ be the sample space associated to a random experiment. Let $P({w_n}) = {{P({w_{n - 1}})} \over 2},n \ge 2$. Let $A = \{ 2k + 3l:k,l \in N\}$ and $B = \{ {w_n}:n \in A\}$. Then P(B) is equal to :

Consider a function $f:\mathbb{N}\to\mathbb{R}$, satisfying $f(1)+2f(2)+3f(3)+....+xf(x)=x(x+1)f(x);x\ge2$ with $f(1)=1$. Then $\frac{1}{f(2022)}+\frac{1}{f(2028)}$ is equal to

The set of all values of $\lambda$ for which the equation ${\cos ^2}2x - 2{\sin ^4}x - 2{\cos ^2}x = \lambda$ has a real solution $x$, is :

The area of the region $A = \left\{ {(x,y):\left| {\cos x - \sin x} \right| \le y \le \sin x,0 \le x \le {\pi \over 2}} \right\}$ is

Let $\overrightarrow a = 4\widehat i + 3\widehat j$ and $\overrightarrow b = 3\widehat i - 4\widehat j + 5\widehat k$. If $\overrightarrow c$ is a vector such that $\overrightarrow c .\left( {\overrightarrow a \times \overrightarrow b } \right) + 25 = 0,\overrightarrow c \,.(\widehat i + \widehat j + \widehat k) = 4$, and projection of $\overrightarrow c$ on $\overrightarrow a$ is 1, then the projection of $\overrightarrow c$ on $\overrightarrow b$ equals :

The value of the integral $\int_1^2 {\left( {{{{t^4} + 1} \over {{t^6} + 1}}} \right)dt}$ is

Let K be the sum of the coefficients of the odd powers of $x$ in the expansion of $(1+x)^{99}$. Let $a$ be the middle term in the expansion of ${\left( {2 + {1 \over {\sqrt 2 }}} \right)^{200}}$. If ${{{}^{200}{C_{99}}K} \over a} = {{{2^l}m} \over n}$, where m and n are odd numbers, then the ordered pair $(l,\mathrm{n})$ is equal to

The value of the integral $\int\limits_{1/2}^2 {{{{{\tan }^{ - 1}}x} \over x}dx}$ is equal to :

The shortest distance between the lines ${{x - 1} \over 2} = {{y + 8} \over -7} = {{z - 4} \over 5}$ and ${{x - 1} \over 2} = {{y - 2} \over 1} = {{z - 6} \over { - 3}}$ is :

Let $f$ and $g$ be the twice differentiable functions on $\mathbb{R}$ such that

$f''(x)=g''(x)+6x$

$f'(1)=4g'(1)-3=9$

$f(2)=3g(2)=12$.

Then which of the following is NOT true?

The total number of 4-digit numbers whose greatest common divisor with 54 is 2, is __________.

Let $X=\{11,12,13,....,40,41\}$ and $Y=\{61,62,63,....,90,91\}$ be the two sets of observations. If $\overline x$ and $\overline y$ are their respective means and $\sigma^2$ is the variance of all the observations in $\mathrm{X\cup Y}$, then $\left| {\overline x + \overline y - {\sigma ^2}} \right|$ is equal to ____________.

Let $\alpha = 8 - 14i,A = \left\{ {z \in c:{{\alpha z - \overline \alpha \overline z } \over {{z^2} - {{\left( {\overline z } \right)}^2} - 112i}}=1} \right\}$ and $B = \left\{ {z \in c:\left| {z + 3i} \right| = 4} \right\}$. Then $\sum\limits_{z \in A \cap B} {({\mathop{\rm Re}\nolimits} z - {\mathop{\rm Im}\nolimits} z)}$ is equal to ____________.

Let $\alpha_1,\alpha_2,....,\alpha_7$ be the roots of the equation ${x^7} + 3{x^5} - 13{x^3} - 15x = 0$ and $|{\alpha _1}| \ge |{\alpha _2}| \ge \,...\, \ge \,|{\alpha _7}|$. Then $\alpha_1\alpha_2-\alpha_3\alpha_4+\alpha_5\alpha_6$ is equal to _________.

Let $\{ {a_k}\}$ and $\{ {b_k}\} ,k \in N$, be two G.P.s with common ratios ${r_1}$ and ${r_2}$ respectively such that ${a_1} = {b_1} = 4$ and ${r_1} < {r_2}$. Let ${c_k} = {a_k} + {b_k},k \in N$. If ${c_2} = 5$ and ${c_3} = {{13} \over 4}$ then $\sum\limits_{k = 1}^\infty {{c_k} - (12{a_6} + 8{b_4})}$ is equal to __________.

Let A be a symmetric matrix such that $\mathrm{|A|=2}$ and \left[ {\matrix{ 2 & 1 \cr 3 & {{3 \over 2}} \cr } } \right]A = \left[ {\matrix{ 1 & 2 \cr \alpha & \beta \cr } } \right]\(. If the sum of the diagonal elements of A is \)s\(, then \)\frac{\beta s}{\alpha^2} is equal to __________.

The ratio of de-Broglie wavelength of an $\alpha$ particle and a proton accelerated from rest by the same potential is $\frac{1}{\sqrt m}$, the value of m is -

A force acts for 20 s on a body of mass 20 kg, starting from rest, after which the force ceases and then body describes 50 m in the next 10 s. The value of force will be:

The equation of a circle is given by $x^2+y^2=a^2$, where a is the radius. If the equation is modified to change the origin other than (0, 0), then find out the correct dimensions of A and B in a new equation : ${(x - At)^2} + {\left( {y - {t \over B}} \right)^2} = {a^2}$. The dimensions of t is given as $[\mathrm{T^{-1}]}$.

A square loop of area 25 cm$^2$ has a resistance of 10 $\Omega$. The loop is placed in uniform magnetic field of magnitude 40.0 T. The plane of loop is perpendicular to the magnetic field. The work done in pulling the loop out of the magnetic field slowly and uniformly in 1.0 sec, will be

Heat energy of 184 kJ is given to ice of mass 600 g at $-12^\circ \mathrm{C}$. Specific heat of ice is $\mathrm{2222.3~J~kg^{-1^\circ}~C^{-1}}$ and latent heat of ice in 336 $\mathrm{kJ/kg^{-1}}$

A. Final temperature of system will be 0$^\circ$C.

B. Final temperature of the system will be greater than 0$^\circ$C.

C. The final system will have a mixture of ice and water in the ratio of 5 : 1.

D. The final system will have a mixture of ice and water in the ratio of 1 : 5.

E. The final system will have water only.

Choose the correct answer from the options given below :

Identify the correct statements from the following :

A. Work done by a man in lifting a bucket out of a well by means of a rope tied to the bucket is negative.

B. Work done by gravitational force in lifting a bucket out of a well by a rope tied to the bucket is negative.

C. Work done by friction on a body sliding down an inclined plane is positive.

D. Work done by an applied force on a body moving on a rough horizontal plane with uniform velocity is zero.

E. Work done by the air resistance on an oscillating pendulum is negative.

Choose the correct answer from the options given below :

A scientist is observing a bacteria through a compound microscope. For better analysis and to improve its resolving power he should. (Select the best option)

Given below are two statements :

Statement I : Electromagnetic waves are not deflected by electric and magnetic field.

Statement II : The amplitude of electric field and the magnetic field in electromagnetic waves are related to each other as ${E_0} = \sqrt {{{{\mu _0}} \over {{\varepsilon _0}}}} {B_0}$.

In the light of the above statements, choose the correct answer from the options given below :

The time taken by an object to slide down 45$^\circ$ rough inclined plane is n times as it takes to slide down a perfectly smooth 45$^\circ$ incline plane. The coefficient of kinetic friction between the object and the incline plane is :

For the given figures, choose the correct options :

An object moves at a constant speed along a circular path in a horizontal plane with center at the origin. When the object is at $x=+2~\mathrm{m}$, its velocity is $\mathrm{ - 4\widehat j}$ m/s. The object's velocity (v) and acceleration (a) at $x=-2~\mathrm{m}$ will be

The time period of a satellite of earth is 24 hours. If the separation between the earth and the satellite is decreased to one fourth of the previous value, then its new time period will become.

The electric current in a circular coil of four turns produces a magnetic induction 32 T at its centre. The coil is unwound and is rewound into a circular coil of single turn, the magnetic induction at the centre of the coil by the same current will be :

A fully loaded boeing aircraft has a mass of $5.4\times10^5$ kg. Its total wing area is 500 m$^2$. It is in level flight with a speed of 1080 km/h. If the density of air $\rho$ is 1.2 kg m$^{-3}$, the fractional increase in the speed of the air on the upper surface of the wing relative to the lower surface in percentage will be. ($\mathrm{g=10~m/s^2}$)

For the given logic gates combination, the correct truth table will be

At 300 K, the rms speed of oxygen molecules is $\sqrt {{{\alpha + 5} \over \alpha }}$ times to that of its average speed in the gas. Then, the value of $\alpha$ will be

(used $\pi = {{22} \over 7}$)

A point charge $2\times10^{-2}~\mathrm{C}$ is moved from P to S in a uniform electric field of $30~\mathrm{NC^{-1}}$ directed along positive x-axis. If coordinates of P and S are (1, 2, 0) m and (0, 0, 0) m respectively, the work done by electric field will be

A particle of mass 100 g is projected at time t = 0 with a speed 20 ms$^{-1}$ at an angle 45$^\circ$ to the horizontal as given in the figure. The magnitude of the angular momentum of the particle about the starting point at time t = 2s is found to be $\mathrm{\sqrt K~kg~m^2/s}$. The value of K is ___________.

(Take g = 10 ms$^{-2}$)

In an experiment of measuring the refractive index of a glass slab using travelling microscope in physics lab, a student measures real thickness of the glass slab as 5.25 mm and apparent thickness of the glass slab as 5.00 mm. Travelling microscope has 20 divisions in one cm on main scale and 20 divisions on vernier scale is equal to 49 divisions on main scale. The estimated uncertainty in the measurement of refractive index of the slab is $\frac{x}{10}\times10^{-3}$, where $x$ is ___________

An inductor of inductance 2 $\mathrm{\mu H}$ is connected in series with a resistance, a variable capacitor and an AC source of frequency 7 kHz. The value of capacitance for which maximum current is drawn into the circuit $\frac{1}{x}\mathrm{F}$, where the value of $x$ is ___________.

(Take $\pi=\frac{22}{7}$)

A particle of mass 250 g executes a simple harmonic motion under a periodic force $\mathrm{F}=(-25~x)\mathrm{N}$. The particle attains a maximum speed of 4 m/s during its oscillation. The amplitude of the motion is ___________ cm.

A metal block of base area 0.20 m$^2$ is placed on a table, as shown in figure. A liquid film of thickness 0.25 mm is inserted between the block and the table. The block is pushed by a horizontal force of 0.1 N and moves with a constant speed. IF the viscosity of the liquid is $5.0\times10^{-3}~\mathrm{Pl}$, the speed of block is ____________ $\times10^{-3}$ m/s.

A car is moving on a circular path of radius 600 m such that the magnitudes of the tangential acceleration and centripetal acceleration are equal. The time taken by the car to complete first quarter of revolution, if it is moving with an initial speed of 54 km/hr is $t(1-e^{-\pi/2})s$. The value of t is ____________.

Unpolarised light is incident on the boundary between two dielectric media, whose dielectric constants are 2.8 (medium $-1$) and 6.8 (medium $-2$), respectively. To satisfy the condition, so that the reflected and refracted rays are perpendicular to each other, the angle of incidence should be ${\tan ^{ - 1}}{\left( {1 + {{10} \over \theta }} \right)^{{1 \over 2}}}$ the value of $\theta$ is __________.

(Given for dielectric media, $\mu_r=1$)

For a charged spherical ball, electrostatic potential inside the ball varies with $r$ as $\mathrm{V}=2ar^2+b$.

Here, $a$ and $b$ are constant and r is the distance from the center. The volume charge density inside the ball is $-\lambda a\varepsilon$. The value of $\lambda$ is ____________.

$\varepsilon$ = permittivity of the medium

When two resistance $\mathrm{R_1}$ and $\mathrm{R_2}$ connected in series and introduced into the left gap of a meter bridge and a resistance of 10 $\Omega$ is introduced into the right gap, a null point is found at 60 cm from left side. When $\mathrm{R_1}$ and $\mathrm{R_2}$ are connected in parallel and introduced into the left gap, a resistance of 3 $\Omega$ is introduced into the right gap to get null point at 40 cm from left end. The product of $\mathrm{R_1}$ $\mathrm{R_2}$ is ____________$\Omega^2$